Solvatochromism Study on the Copper(II) Complexes Containing 3–Substituted Derivatives of Acetylacetonate Ligands

سال انتشار: 1390
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 675

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شناسه ملی سند علمی:

JR_IJEE-3-1_012

تاریخ نمایه سازی: 1 اردیبهشت 1393

چکیده مقاله:

Solvatochromic properties of a series of bis(3–substituted derivatives of acetylacetone)copper(II) (X-acacH , X = Cl, H. CH ) complexes were studied. All the complexes demonstrated negative 3 solvatochromism.Among the complexes the Cu(Cl-acac) , demonstrated the most solvatochromism. A multi-parametric equation 2has been utilized to explain the solvent effect on the d-d transition of the complexes using SPSS/PC software.The stepwise multiple linear regression (SMLR) method demonstrated that the donor power of the solvent plays the most important role in the solvatochromism of the compounds

نویسندگان

hamid golchoubian

Department of Inorganic Chemistry, The University of Mazandaran, Babolsar,Iran. Postal Code ۴۷۴۱۶-۹۵۴۴۷

fariba khoshsiar

Department of Inorganic Chemistry, The University of Mazandaran, Babolsar,Iran. Postal Code ۴۷۴۱۶-۹۵۴۴۷