Preparation and Characterization of Polycaprolactone/x%Cu-MOF Nanofibers
محل انتشار: بیست و یکمین سمینار شیمی معدنی انجمن شیمی ایران
سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 383
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شناسه ملی سند علمی:
IICC21_090
تاریخ نمایه سازی: 5 آذر 1398
چکیده مقاله:
Nowadays, porous compounds especially polymeric nanofibers mats have been the subject of intense research in biological applications such as wound dressing, drug delivery, and tissue engineering [1-2]. MOFs are porous crystalline structures consisting of metal ions (or metal clusters) linked through organic linkers [3]. The main objective of the present work is the fabrication of fibrous composites from blending the Cu-MOF with poly(caprolactone) by electrospinning technique. The as-prepared compounds were characterisized by various techniques including FT-IR, PXRD, EDS mapping, SEM, and TEM.Polycaprolactone/x%Cu-MOF nanofibers by a two-step method including a hydrothermal and electrospinning process for the preparation of Cu-MOFs and PCL/x%Cu-MOF nanocomposites. The results of FT-IR, XRD, and EDS mapping were confirmed the incorporation of Cu-MOF into polycaprolactone matrix. TEM and SEM images showed that the fabricated compounds have nanofiberous morphology. Figure 1 depicts the SEM images of PCL and PCL/20%Cu-MOF nanocomposites. The SEM images revealed that PCL fibers have continuous and cylindrical shape (Figure 1a).Figure 1b shows that the morphology of PCL nanofibers wasn’t changed during composite preparation
نویسندگان
Zeinab Ansari-Asl
Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran
Mohammad Reza Ramezani
Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran