Vapor-liquid and liquid-liquid equilibrium for aqueous solutions containing of Choline-based Deep Eutectic Solvent and PPG400 at 298.15 K

سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 448

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شناسه ملی سند علمی:

ISPTC21_222

تاریخ نمایه سازی: 30 دی 1397

چکیده مقاله:

Deep eutectic solvents (DES) have emerged in the past few years as a new class of solvents withpromising applications in several fields [1]. For designing of industrial processes, it is essential to obtainvapor pressure data for these solvents especially in water media. From this view point, in this work wefocused our attention on the study of vapor-liquid equilibria (VLE) of ternary {Choline Chloride/sucrose+ PPG400 + water} system at 298.15 K [2,3]. From this study water activity has been obtained using theimproved isopiestic method. This investigation shows that PPG is able to form an aqueous biphasicsystem with DES above a certain concentration. This is indeed what we observed experimentally bystudying liquid-liquid equilibrium [4].

نویسندگان

Fariba Ghaffari Hashjin

Physical Chemistry Department, University of Tabriz, Tabriz, Iran

Mohammad Taghi Zafarani-Moattar

Physical Chemistry Department, University of Tabriz, Tabriz, Iran

Hemayat Shekaari

Physical Chemistry Department, University of Tabriz, Tabriz, Iran