Adsorption, isotherms and kinetics characteristics of solid state Mg exchanged bentonite for removal of methylene blue

This study investigated the removal of methylene blue dye from aqueous solutions using Mg solid state exchanged bentonite. Parent bentonite and magnesium exchanged bentonite were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer Emmett Teller (BET), Energy dispersive X-ray spectroscopy (EDX), and Fourier transform infrared spectroscopy (FTIR). The parent bentonite showed the lowest removal efficiency (۴۰.۳%) and prepared magnesium exchanged bentonite for ۱۰ min showed the highest removal efficiency (۵۴.۸%). Thus, dye absorption by modified bentonite increased compared to parent bentonite. After its modification by the ion exchange method, the specific surface was changed from ۴۴.۵ to ۵۶.۰۵ M۲/g. EDX results indicate that the cation exchange process has been completed successfully. Ion exchange causes some minor changes in bentonite morphology and crystallinity. The best conditions for removing methylene blue using magnesium exchanged bentonite was pH ۱۰, adsorbent dosage ۰.۰۵ mg/liter, initial concentration of solution ۱۰۰ mg per liter, and contact time of ۱۲۰ minutes with a Removal efficiency of ۹۶.۶۷. The Langmuir isotherm had a better correlation coefficient than the Freundlich adsorption model, which indicated the homogeneous surface of the adsorbent.

کلیدواژه ها:

Adsorption ، Magnesium ، Solid state exchange ، Bentonite