The Use of Silica@Zn+۲ as an efficient catalyst in Diels–Alder reactions

In this study, the application of the Diels-Alder cycloaddition reactions between methyl acrylate and cyclopentadiene has been studied using a silica-supported catalyst with various concentrations of Zn۲+ ion (Silica@Zn+۲) as Lewis acid catalyst without using the solvent. The effective role of silanol groups in increasing stereoselectivities of products was also studied.

کلیدواژه ها:

Diels-Alder reaction ، Silica support ، Cyclopentadiene ، Methylacrylate ، Silica@Zn+۲