The Use of Silica@Zn+۲ as an efficient catalyst in Diels–Alder reactions
محل انتشار: فصلنامه شیمی آلی-فلزی کاربردی، دوره: 1، شماره: 4
سال انتشار: 1400
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 244
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شناسه ملی سند علمی:
JR_JAOC-1-4_004
تاریخ نمایه سازی: 3 بهمن 1400
چکیده مقاله:
In this study, the application of the Diels-Alder cycloaddition reactions between methyl acrylate and cyclopentadiene has been studied using a silica-supported catalyst with various concentrations of Zn۲+ ion (Silica@Zn+۲) as Lewis acid catalyst without using the solvent. The effective role of silanol groups in increasing stereoselectivities of products was also studied.
کلیدواژه ها:
نویسندگان
G. Mohammadi Ziarani
Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran
Soheila Afsharnia
Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran
alireza badiei
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
Negar Lashgari
Department of Chemistry, Faculty of physics and Chemistry, Alzahra University, Tehran, Iran