Solvent Effects on Proto nation an d Comple xation of Aspartic A cids with Molybden um(VI) i n Different Aqueous Solutions of Methanol

Chemists are usually interested to understan d solvent effects on overall solution capabilities that depe nd on all po ssible inter molecular in teractions between solute and solve nt molecules. Solvent effects on transition metal complex es are revie wed and mo re attention has been paid to binary solvent mi xtures in this field. Solute-solvent interactions are much more complex in mixed so lvent syste ms than in pure solvent due to the possibility of preferential solvation b y any of the solvent present in the mixtu res. Moreov er, the solvent-solvent interactio ns produced in solvent mixtures ca n affect the solute-solvent interactions and there fore they ca n also affect preferential solvation s.