Biodisel Production by Esterification of Oleic Acid with Ethanol Using a Magnetic Activated Carbon Nanocatalyst (Fe۳O۴@SiO۲ /AC)
محل انتشار: دومین کنفرانس کاتالیست انجمن شیمی ایران
سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 484
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شناسه ملی سند علمی:
ICCO02_101
تاریخ نمایه سازی: 3 اردیبهشت 1399
چکیده مقاله:
The esterification of free fatty acids (FFA) mostly found in vegetable oils with ethanol using solid acid catalyst is one of promisingmethod to convert FFA into Fatty Acid Ethyl Ester (FAEE) that is an alternative to replace fossil fuel as energy source mostly intransportation sector. The present study aimed to determine the optimum or best operating condition for the production of FAEE byesterification of oleic acid and ethanol with a new magnetic activated carbon nanocatalyst (Fe۳O۴ /AC) as solid acid catalyst.The novel catalyst was characterized by FTIR, SEM, XRD, TGA and BET. The scope of study, the achieving optimum operatingcondition of oleic acid esterification at ۵۰-۸۰°C, ۰.۵-۱.۵ g Fe۳O۴ /AC solid catalyst and ۵:۱, ۱۰:۱, ۱۵/۱ ethanol to oleic acid molarratio that brings maximum% oleic acid conversion.
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نویسندگان
Maryam Razavi Mehr
Department of Chemistry, Ayatollah Boroujerdi University, boroujerd, Iran
Hossein Rouhbakhsh
Department of Chemistry, Ayatollah Boroujerdi University, Boroujerd, Iran
Mohammad Hossein Fekri
Department of Chemistry, Ayatollah Boroujerdi University, Boroujerd, Iran
Javad Torkashvand
Department of Chemistry, Ayatollah Boroujerdi University, Boroujerd, Iran