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اُستادیار ؛ عضو هیات علمی دانشگاه آزاد اسلامی واحد علوم و تحقیقات تهران
492 یادداشت منتشر شدهInvestigation of The Purification of Nanofullerenes by Column Chromatography For The Manufacture of Nanoelectronic Devices and instruments

Note: Purification of nano-fullerenes is usually accomplished by high-performance column chromatography. On a smaller scale, sublimation can also be used to produce solvent-free fullerenes of high purity. Fullerenes are dark, sooty solids that are sometimes shiny.
The solubility of fullerenes in hydrocarbon solvents is usually negligible, but in aromatic nanomolecule solvents it is high, and in nanostructured compounds larger fullerenes are less soluble than smaller fullerenes. This class of nanostructured compounds was first obtained by the electrical discharge method. Of course, the exact mechanism for the formation of fullerenes is not known, but it seems that they are produced during the creation of carbon plasma. Purification of fullerenes is usually carried out by high-performance column chromatography. Also, on a smaller scale, sublimation can be used to produce solvent-free fullerenes of high purity. Fullerenes are sooty, dark-colored solids and in some cases shiny. The solubility of fullerenes in hydrocarbon solvents is usually negligible, but in aromatic nanomolecule solvents it is high, and in nanostructured compounds larger fullerenes are less soluble than smaller fullerenes. Buckyballs can return to their original shape when compressed and rotate at an astonishingly high speed.

Fullerenes are the constituent particles of buckyballs in electrically conductive nanodevices. Buckyballs and fullerenes are among the materials on which many nanomaterials are based. One of the most important and unique properties of fullerenes is their ability to retain atoms or small molecules within a carbon cage. The importance of spatial and electronic parameters associated with the cage structure, such as fullerenes, in the factors of this importance is the inclusion of nanostructures and the stability of these compounds. The optical properties, ionization energies and electronegativity, and relative stability of different polymorphisms of fullerenes are very influential in the proliferation of nanoelectronic devices.

Nanofullerenes can be defined as materials that have at least one external dimension in the range of 1 to 100 nm. And the particle size of at least half of the particles in the number size distribution must be 100 nm or less. In nanoelectronics, nanofullerenes can occur naturally, be produced as by-products of combustion reactions, or be purposefully engineered to perform a specific function. These materials can have different physical and chemical properties from their original bulk counterparts. Nanofullerenes are used in composites to bend in response to the application of an electrical voltage.

The use of nano-fullerenes is widespread in a wide range of industries and consumer products. In nanoscience, the structure of materials determines the relationships between atoms, ions, and molecules that make up those materials. To understand the structure of materials, one must first understand the types of connections between atoms and ions . Chemical bonds determine the way atoms and ions are connected. Therefore, the differences between different types of connections can be seen in the characteristics of these bonds.
Conclusion :
Purification of nanofullerenes is usually accomplished by high-performance column chromatography. On a smaller scale, sublimation can also be used to produce solvent-free fullerenes of high purity. Fullerenes are dark, sooty solids that are sometimes shiny.