Electrochemical Synthesis and Characterization of Cobalt Complex Nano-Catalyst for Water Splitting Application
سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 329
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شناسه ملی سند علمی:
IMES13_187
تاریخ نمایه سازی: 13 آبان 1398
چکیده مقاله:
In water splitting electrolysis, oxygen evolution reaction is the most challengeable one because it needs much overpotential, decreasing the water electrolysis efficiency. Accordingly, searching for a catalyst with the least amount of over-potential for water oxidation is inevitable. In this study, the cobalt phosphate complex synthesized by electrochemical deposition resulting in nano morphology noticeably decreased the over-potential and increased the current density. Compared to the newest reported studies, the voltage decreased by 0.1 V and the current density increased up to 200 micro-amp indicating 25% higher efficiency. Cyclic voltammetry, chronoamprometry and polarization techniques were used for corroborating the electro-catalytic improvement and SEM was used for proving the nano morphology. Cobalt-based nano-catalyst has many elements of natural photosynthesis, such as low over-potential, neutral pH and 1 atm pressure at room temperature
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نویسندگان
E Loni
PhD Student, Faculty of Materials Science & Engineering, K. N. Toosi University of Technology, Tehran, Iran
H Siadati
Associate Professor, Faculty of Materials Science & Engineering, K. N. Toosi University of Technology, Tehran, Iran
A Shokuhfar
Professor, Faculty of Materials Science & Engineering, K. N. Toosi University of Technology, Tehran, Iran