Preparation, Characterization and Computational Studies of Mercury (II) Complex with 1-(P-Tolyl)-2-(Tri-P-Tolyl- Λ5-Phosphanylidene) Ethan-1-One
سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 352
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شناسه ملی سند علمی:
TECHSD04_061
تاریخ نمایه سازی: 31 تیر 1398
چکیده مقاله:
The α-phosphorus ligand of 1-(p-tolyl)-2-(tri-p-tolyl- λ5-phosphanylidene) ethan-1-one (L) was prepared. The reactions of the ligand L with mercury (II) and cadmium (II) ions in (1:1) ratio by dry methanol as solvent resulted [(p-tolyl)3PCHCOC6H4CH3. CdCl2]2 C1 and [(p-tolyl)3PCHCOC6H4CH3 . HgBr2]2 C2. The solid state structure of C2 was detected by X-ray crystallography analysis and its Computational studies at DFT)B3LYP/6-31G*) level of theory are also reported.
کلیدواژه ها:
نویسندگان
Ali Reza Dadrass
Urmia University Department of Chemistry, Faculty of Science Urmia,Iran
Mahsa Pourmirza
Urmia University Department of Chemistry, Faculty of Science Urmia,Iran
Shahla Ebrahimnezhad
Urmia University Department of Chemistry, Faculty of Science Urmia,Iran
Sholeh. Alaei
Azad University of Urmia - Site ۳ Faculty of Science Urmia,Iran