Carbon disulfide production via hydrogen sulfide methane reformation

سال انتشار: 1388
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 2,688

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شناسه ملی سند علمی:

ICHEC06_288

تاریخ نمایه سازی: 1 مهر 1388

چکیده مقاله:

Carbon disulfide is widely used for the production of viscose rayon, rubber, and other organic materials and it is a feedstock for the synthesis of sulfuric acid. The objective of this paper is to analyze possibilities for efficient production of CS2 from sour natural gas reformation (H2SMR) (2H2S+CH4 =CS2 +4H2). Also, the effect of H2S to CH4 feed ratio and reaction temperature on carbon disulfide production is investigated numerically in a reforming reactor. The chemical reaction model is based on an assumed Probability Density Function (PDF) parameterized by the mean and variance of mixture fraction and β-PDF shape. The results show that the major factor influencing CS2 production is reactor temperature. The yield of carbon disulfide increases with increasing H2S to CH4 feed gas ratio (H2S/CH4≤4). Also the yield of C(s) increases with increasing temperature until the temperature reaches to 1000°K, and then due to increase of CS2 production and consumption of C(s), yiel of C(s) drops with further increase in the temperature. The predicted CH4 and H2S conversion and yield of carbon disulfide are in good agreement with result of Huang and TRaissi.

نویسندگان

Mohammad Javadi

Department of Mechanical Engineering Ferdowsi University, Mashad, Iran

Fatemeh Golkhou

Department of Chemical Engineering Ferdowsi University, Mashad, Iran

Nasrin Sheikhy

Department of Mechanical Engineering Ferdowsi University, Mashad, Iran

Mohammad Moghiman

Department of Mechanical Engineering Ferdowsi University, Mashad, Iran

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