Mesoporous SiO2 immobilized HClO4 for synthesis of DHPMs and DHPs Heterocycles
محل انتشار: چهارمین کنفرانس ملی زئولیت ایران
سال انتشار: 1396
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 551
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شناسه ملی سند علمی:
NZEOLITE04_012
تاریخ نمایه سازی: 11 شهریور 1397
چکیده مقاله:
Recently, ordered mesoporous silica of SBA-15 has emerged as a catalyst in various organic transformations, especially when low amount of catalyst loading of the catalyst are used [1-3]. Based on our interest in multicomponent reactions [4-6], in this respect, we are used a neat heterogeneous and reusable catalytically ordered mesoporous silicasupported perchloric acid (SBA-15/HClO4) mediate for ring-opening reaction of diketene6 in presence of alcohols and aldehydes for preparation of the DHPMs and DHPs heterocycles via urea and ammonium acetate as nuclephile, respectively (Figure 1). The neat approach, simplicity and variability in derivatives of the present four-componentprocedure makes it an interesting alternative to three-component usual approaches
نویسندگان
Sadegh Rostamnia
Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P.O.B ۵۵۱۸۱-۸۳۱۱۱, Maragheh, Iran