Adsorption and Desorption of Sulfur Compounds by Improved Nano Adsorbent: Optimization Using Response Surface Methodology

سال انتشار: 1396
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 133

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شناسه ملی سند علمی:

JR_IJCCE-36-4_008

تاریخ نمایه سازی: 17 خرداد 1404

چکیده مقاله:

Today, sulfur removal from fuels has improved by new adsorbents such as zeolites that needs extensive studies. This study investigates the feasibility of sulfur compounds adsorption on improved nano zeolite existing in organic fuels and desorption of them from nano-adsorbent.Some properties of improved nano zeolite were analyzed to receive better sulfur compounds adsorption. Zeolite surface structure was analyzed by TEM (tunneling electron microscopy). Batch experiments were chosen for adsorption/desorption study of sulfur compounds and adsorption and desorption conditions were optimized by BBD methodology. The influence of variables in the process, consists of adsorbent metal percent (۰.۰۵-۱۰  wt%), adsorbent calcination temperature (۲۰۰-۵۰۰ °C) and adsorption process temperature (۳۰-۱۲۰ °C) in adsorption stage and gas flow rate (۱.۵-۳.۵ mL/Min), regeneration temperature (۱۵۰-۳۰۰ °C) and desorption time (۳۰-۹۰ Min) which were investigated using experimental design procedure.

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نویسندگان

Ghasem Bakhtiari

Chemistry Department, Amirkabir University of Technology, P.O. Box ۱۵۸۷۵-۴۴۱۳, Tehran, I.R. IRAN

Mansour Bazmi

Refining Technology Development Division, Research Institute of Petroleum Industry, Tehran, I.R. IRAN

Majid Abdouss

Chemistry Department, Amirkabir University of Technology, P.O. Box ۱۵۸۷۵-۴۴۱۳, Tehran, I.R. IRAN

Sayed Javid Royaee

Refining Technology Development Division, Research Institute of Petroleum Industry, Tehran, I.R. IRAN

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