Synthesis of a Novel Cyclotriphosphazene by Using Xanthydrol Oxygen Containing Ligand

A new derivative of Cyclotriphosphazene with xanthydrol as the oxygen-containing ligand was synthesized. Firstly Hexaclorocyclotriphosphazene was obtained Hexaclorocyclotriphosphazene from ammonium chloride and phosphorus pentachloride reaction and then the deprotonated xanthydrol was reacted with Hexaclorocyclotriphosphazene in the ratio of ۶:۱ in dry toluene as the solvent. All of the Cl atoms were substituted with hydroxyl groups of ligand to give a new product with (NP (C۱۴H۱۰O) ۲)۳ formula. This product was identified by a series of spectroscopic techniques including FTIR, ۳۱P NMR, ۱۳C NMR, ۱H NMR and mass spectroscopy. Analyses were performed to confirm the formation of the designed product and structure.

کلیدواژه ها:

Hexaclorocyclotriphosphazene ، oxygen containing ligand ، xanthydrol ، Cyclotriphosphazene