Removal of polypropylene nanoplastics from aqueous solution by biochar derived from Date palm fibers: Kinetics and isotherms studies

In this work, activated carbon (AC) derived from powder of date palm fibers (DPF) was examined as an adsorbent for removing polypropylene nanoplastics (PPNPs) from aqueous solutions. The adsorbent was characterized using XRD, FT-IR, and SEM analyses. Affecting parameters on removal efficiency in a batch reactor, such as contact time, concentration of PPNPs and amount of adsorbent,were evaluated and optimized.Equilibrium and kinetic studies are performed tounders tand adsorption mechanisms.In the batch sys tem, ۳۰ mL of polypropylene suspension (۵-۴۰ mgL-۱) was addedto Erlenmeyer flask. First, different amounts of AC adsorbent were added to the container, then microplastic was added to the reactor.The mixture was shaken on a shaker for four hours at ۲۵oC. The flask was removed from the shaker, the concentration of PPNPs in the supernatant was measured, and a settling time of ۳۰ min was obtained. A control suspension system without PPNPs nanoplastics (with biochar and without PPNPs) was also performed to evaluatecarbon particle interference by turbidity measurements.Our results showed that kinetic data were consis tent with the pseudo-second-order kinetic model. Equilibrium data for the adsorption of PPNPs on biochar represented by the Langmuir isotherm model is better than the Freundlich isotherm model.

کلیدواژه ها:

Adsorption ، Activated carbon ، Polypropylene nanoplas tics ، Date ، Kinetics ، Isotherm