Cyclometalated piano-stool Iridium(III) complexes: structural Characterization andtheoretical calculations
سال انتشار: 1403
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 83
نسخه کامل این مقاله ارائه نشده است و در دسترس نمی باشد
- صدور گواهی نمایه سازی
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
NICEC22_566
تاریخ نمایه سازی: 7 مرداد 1403
چکیده مقاله:
This study aims to synthesize and characterize new Ir(III) complexes based on the ۲-(۲,۴-difluorophenyl)pyridine (dfppy) cyclometalated ligand. Various analytical techniques, including HR ESI-MS, NMRspectroscopy, and X-ray diffraction crystallography were employed to characterize the complexes. Additionally,UV-Vis absorption spectra were recorded and compared with theoretical calculations using DFT and TD-DFTmethods. The results provide insights into the electronic transitions and photophysical properties of thecomplexes.
کلیدواژه ها:
نویسندگان
Mahya Ghaffari
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan ۴۵۱۳۷-۶۶۷۳۱, Iran.
Mahshid Nikravesh
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan ۴۵۱۳۷-۶۶۷۳۱, Iran.
Hamid R. Shahsavari
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan ۴۵۱۳۷-۶۶۷۳۱, Iran.