Synthesis of allyl acrylate and ۱,۲-ethanedithiol copolymers via Thiol-Ene click reactionand investigating the effect of initiator on polymerization

Sulfur-containing polymers have many important useful characteristics, such as mechanical, electrical,and optical properties. Thiol-ene photopolymerization is a fast, controllable, and easy method in mild reactionconditions with no or minimal side products formation for the synthesis of sulfur-containing polymers. In thisstudy, sulfur-containing polymers with linear and cross-linked structures were successfully synthesized usingthiol-ene reactions, and it was discovered that the presence of a radical initiator has caused the polymer chainsto form cross-links.

کلیدواژه ها:

Sulfur-containing polymers ، thiol-ene polymerization ، linear polymer ، cross-linked polymer ، radicalinitiator.