Green Synthesis of CuO -Ni Foam Heterojunction nanoparticles via Dip-Coating forEfficient Visible Light Photocatalytic Oxidation of Benzyl Alcohol to Benzaldehyde

سال انتشار: 1403
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 80

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شناسه ملی سند علمی:

NICEC22_499

تاریخ نمایه سازی: 7 مرداد 1403

چکیده مقاله:

The CuO-Ni foam heterojunction nanoparticles was prepared using a sustainable Green synthesisapproach known as Dip-coating. This innovative method enabled the in-situ photocatalytic oxidation of benzylalcohol (BA) to aldehydes when exposed to visible light. The CuO catalyst supported on a nickel foam bed playeda crucial role in catalyzing the conversion of benzyl alcohol to benzaldehyde. Subsequently, the benzaldehydeunderwent condensation with o-phenylenediamine, yielding a diverse array of ۲-substituted benzimidazoles.These compounds serve as vital intermediates in pharmaceutical synthesis. The photocatalytic reaction occurredunder green laser light with a wavelength of ۵۳۵ nm. The reaction was conducted in water at ۴۰°C for a durationof ۶۰ minutes, resulting in an impressive efficiency of ۸۹%. The nanocomposite was meticulously characterizedusing a range of analytical techniques including FT-IR, XRD, FESEM, and Matt Schottky analysis

نویسندگان

Reza Taeybee

Department of Chemistry, Faculty of Science, Hakim Sabzevari University, Sabzevar, Iran.

Sedighe Abbaspour

Department of Chemistry, Faculty of Science, Hakim Sabzevari University, Sabzevar, Iran.

Zahra Jalili

Department of Chemistry, Faculty of Science, Hakim Sabzevari University, Sabzevar, Iran.

Farrokhzad Mohammadi Zonoz

Department of Chemistry, Faculty of Science, Hakim Sabzevari University, Sabzevar, Iran.