Efficient Oxidative Dehydrogenation of Dihydropyrimidinones and Thiocyanation of Aromatic Compounds Using ۱,۱,۲,۲-Tetrahydroperoxy-۱,۲-diphenylethane as the Oxidant
محل انتشار: دوفصلنامه تحقیقات شیمی آلی، دوره: 5، شماره: 2
سال انتشار: 1398
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 46
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شناسه ملی سند علمی:
JR_ORGC-5-2_003
تاریخ نمایه سازی: 3 مهر 1402
چکیده مقاله:
A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using ۱,۱,۲,۲-tetrahydroperoxy-۱,۲-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized and next under the optimized reaction conditions the desired products were yielded after an easy work-up and the structures were characterized compared with those reported. All of the reactions proceeded in short reaction times and ۱,۱,۲,۲-tetrahydroperoxy-۱,۲-diphenylethane (THPDPE) proved its potential to yield the desired products in high yields.
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نویسندگان
Kaveh Khosravi
Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.
Amir Azizi
Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran
Shirin Naserifar
Faculty of Science, Department of Chemistry, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran.