MNPs-TBAN as a Novel Basic Nanostructure and Efficient Promoter for the Synthesis of Pyranopyrimidinones
محل انتشار: دوفصلنامه تحقیقات شیمی آلی، دوره: 6، شماره: 2
سال انتشار: 1399
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 75
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شناسه ملی سند علمی:
JR_ORGC-6-2_012
تاریخ نمایه سازی: 3 مهر 1402
چکیده مقاله:
In this study, magnetite nanoparticles (Fe۳O۴) were synthesized as a magnetic core by chemical co-precipitation process and coated with a silica layer. The (Fe۳O۴@SiO۲) core-shell magnetic nanoparticles were functionalized by organic-base tags to produce the MNPs-TBAN nanoparticles as a novel hybrid nanostructure. The morphology, stability, and magnetism of this hybrid nanostructure were characterized and studied by Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), vibrating sample magnetometry (VSM), X-ray powder diffraction analysis (XRD), scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The prepared hybrid nanomaterial was successfully used as a basic heterogeneous catalyst for the synthesis of pyrano[۲,۳-d]pyrimidine derivatives, via the condensation of an aldehyde, malononitrile and barbituric acid or thiobarbituric acid. The reaction was afforded the desired products in high purity and has advantages of excellent yields, simple workup procedure, and short reaction time. The catalyst was easily separated from the reaction mixture with the assistance of an external magnet and reused for several runs without noticeable deterioration in catalytic activity.
کلیدواژه ها:
نویسندگان
Elham Khalili
Department of Chemistry, Faculty of Science, Arak University, Arak ۳۸۱۵۶-۸۸۱۳۸, Iran
Najmieh Ahadi
Institute of Nanosciences & Nanotechnology, Arak University, Arak, Iran.
Mohammad Ali Bodaghifard
Department of Chemistry, Faculty of science, Arak University, Arak ۳۸۱۵۶-۸-۸۳۴۹, Iran