Application of MIL-101(Cr) in the Synthesis of N-Amino-2-pyridones and 1,4-Dihydropyrano[2,3-c]pyrazoles
محل انتشار: بیست و ششمین سمینار شیمی آلی ایران
سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 470
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شناسه ملی سند علمی:
ISOC26_121
تاریخ نمایه سازی: 2 شهریور 1398
چکیده مقاله:
In recent years, metal–organic frameworks (MOFs) have been considered as a new categoryof nano-porous materials which are suitable for storage and separation of gases, catalysts,heavy metal adsorbents. MOFs, based on the type of ligand and functional groups on theirsurface, exhibit various properties. MOFs exhibit a unique catalytic role in the preparation ofhydrogen and methane gas and the synthesis of a wide range of chemical and pharmaceuticalcompounds [1-2]. N-Amino-2-pyridones and 1,4-dihydropyrano [2,3-c]pyrazoles have beenapplied to the treatment of rheumatoid arthritis, psoriasis, cancer, Parkinson’s disease, Huntington’sdisease, Alzheimer’s disease, Down’s syndrome, AIDS, schizophrenia, and myoclonusas well as demonstrating biological properties such as antiviral, , pheromonal, and centralnervous system activity [3-4]. In this work, we have designed and synthesized a MOF, MIL-101(Cr), as an efficient catalyst for promoting the described four components reactions underrefluxing water conditions (Fig. 1).
نویسندگان
Saeed Babaee
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Mahmoud Zarei
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Hassan Sepehrmansourie
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran
Mohammad Ali Zolfigol
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan ۶۵۱۷۸۳۸۶۸۳, Iran