Modified Mesoporous TiO2-SiO2 Catalyst for Oxidative Desulfurization of Dibenzothiophene
محل انتشار: شانزدهمین کنگره ملی مهندسی شیمی ایران
سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 504
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شناسه ملی سند علمی:
NICEC16_243
تاریخ نمایه سازی: 7 خرداد 1398
چکیده مقاله:
The principal objective of this study was to develop a modified TiO2-SiO2 catalyst by a sol-gel method for oxidative desulfurization (ODS) of dibenzothiophene (DBT) as a refractory sulfur compound of liquid fuels. TiO2-SiO2 catalysts were prepared using tetra-n-butyl orthotitanate (TBOT) as titania precursor and tetraethyl orthosilicate (TEOS) as silica precursor. The oxidation of DBT was performed with tert-buthyl hydroproxide (TBHP) as the oxidant in the presence of the synthesized catalyst and the best result showed 98% desulfurization for the catalyst containing 7 wt% TiO2 (Ti-Si/7). However, DBT removal reduced to 20% in the present of a competitive nitrogen compound.
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نویسندگان
Seyedeh Fatemeh Musavi
Catalysis and nanomaterials research Laboratory, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
Amin Bazyari
Catalysis and nanomaterials research Laboratory, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
Seyed Mahdi Alavi
Catalysis and nanomaterials research Laboratory, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.