Synthesis of nanocrystallinepolytriazolecalix[4]amides as a new mesogenic polymer and investigation of their thermophysical properties

calixarenes as one of the outstanding organic compounds that has drawn extensive utility since its first preparation plays an important role in the field of supramolecular chemistry [1,2].The chemical modification of calixarene provides a versatile route for structural and property design of such materials.Currently, exploration of new derivatives of calix[4]arene which can be incorporate into the polymeric structures whether in the backbone or as a side groups is a subject ofenduring interest in the area of calix[4]arene chemistry. Herein, we have prepared a new polymerizable derivative of calix[4]arene via the emerging field of synthetic chemistry known as click reaction. The click reactions presents advantageous characteristics such as high efficiency inproduct formation, wide in scope, regio-and stereoselectivity,and functionality tolerance. In this regard and according to our previous work we introduce the preparationof nanocrystallinepolytriazolecalixamides with good solubility and low Tgs that possess some interesting thermo physical properties of polyamides in conjugation with calixarene inherent specificity in sorption of transition metal ions.