Copolymerization of 1-hexene and 1,5 hexadiene by a Fe-dopped Zigler-Natta catalyst

The aim of this study was to incorporate 1,5 hexadiene in the 1-hexene chain, using a Zigler-Natta catalyst system. To this end, 81 mmol of 1-hexene was copolymerized with 25 mmol of 1,5-hexadiene using Mg(OEt)2/FeCl3/TiCl4/DNBP catalyst. After copolymerization, its microstructure was analyzed by HNMR analysis. According to HNMR results, 8 % unsaturation and 12 % cyclization (20 % total 1,5-hexadiene incorporation) were obtained for the synthesized copolymer

کلیدواژه ها:

copolymerization ، poly 1-hexene ، 1 ، 5-hexadiene ، mechanical properties