Synthesis of Hyperbranched 1,4-cis+1,2-Polybutadiene in aControlled One-step way by Using Novel Catalytic DithioSystem
سال انتشار: 1395
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 346
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شناسه ملی سند علمی:
CHECONF03_202
تاریخ نمایه سازی: 14 آذر 1395
چکیده مقاله:
Cobalt Diethyldithiocarbamate + Ethylaluminumsesquichloride used as a catalyst for the synthesis of hyperbranched, low solution viscosity, high molecular weight 1,4-cis-polybutadiene containing 20-40% of 1,2-vinyl bonds. The effect of solvent used, catalyst and monomer concentrations,Al:Co ratio, temperature, polymerization time, polymer microstructure, intrinsic viscosity, molecular mass distribution, branching index on conversion of butadiene were studied as controlling parameters. Polymerization process was carried out in one step by controlled radical-coordination mechanism. The productivity of the used catalyst is 20.0-50.0 kg Polymer/g Co∙h with the 86.0-99.0 % yield ofpolybutadiene. The obtained hyperbranched polybutadiene samples have branching indexes 0.30- 0.75. Synthesized hyperbranched 1,4-cis+1,2-polybutadiene has been used in transdermal drug delivery system.
کلیدواژه ها:
نویسندگان
Shahab Akhyari
Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences
Fizuli Nasirov
Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences
Nazil Janibayov
Institute of Petrochemical Processes of Azerbaijan National Academy of Sciences