Thermodynamic Modelling of Solid-Liquid Equilibria for the Solution of Isotactic Poly (1-Butene) in Different Solvents
محل انتشار: پنجمین کنگره بین المللی مهندسی شیمی
سال انتشار: 1386
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 1,342
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شناسه ملی سند علمی:
ICHEC05_236
تاریخ نمایه سازی: 7 بهمن 1386
چکیده مقاله:
The UNIQUAC activity coefficient model is extended to predict solid-liquid equilibria of isotactic crystalline poly (1-butene), iPBu-1, in different organic solvents. The activity coefficient model used in this work is based on the concept of group-contribution and consists of combinatorial, residual and free volume terms. To account for branching of atom groups in the monomer structure of the polymer, a correction factor has been applied to the surface parameter of combinatorial and residual terms. Use of this correction factor has significantly improved the accuracy of the model and shows that the proposed activity coefficient model is a proper model for solid-liquid equilibria calculations in polymer solutions.
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نویسندگان
Hossein Salimnezhad
Chemical Engineering Faculty, Iran University of Science and Technology Tehran ۱۶۸۴۶, Iran
Farzaneh Feyzi
Chemical Engineering Faculty, Iran University of Science and Technology Tehran ۱۶۸۴۶, Iran