Electrooxidation of Formic Acid and Formaldehyde on the Fe۳O۴@Pt Core-Shell Nanoparticles/Carbon-Ceramic Electrode

سال انتشار: 1395
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 47

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شناسه ملی سند علمی:

JR_IJCCE-35-4_011

تاریخ نمایه سازی: 17 خرداد 1404

چکیده مقاله:

In the present work, the electrooxidation of formic acid and formaldehyde; potentially important fuels for future fuel cells, was investigated on the Fe۳O۴@Pt core-shell nanoparticles/carbon-ceramic electrode (Fe۳O۴@Pt/CCE). The Fe۳O۴@Pt nanoparticles were prepared via a simple and fast chemical method and their surface morphology, nanostructure properties, chemical composition, crystal phase, and electrochemical behavior were investigated by scanning electron microscope, transmission electron microscope, X-ray diffraction, energy dispersive X-ray spectroscopy and electrochemical methods, respectively. Then the electrocatalytic activity of the Fe۳O۴@Pt/CCE toward the oxidation of formic acid and formaldehyde was studied in details. The primary electrochemical analysis shows that the Fe۳O۴@Pt/CCE has superior catalytic activity and stability for formic acid and formaldehyde oxidation compared to Pt-alone nanoparticles on the carbon-ceramic electrode (Pt/CCE). The present investigation demonstrates that the Fe۳O۴@Pt/CCE electrocatalyst may play a significant role in future fuel cell applications.

نویسندگان

Biuck Habibi

Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz, I.R. IRAN

Serveh Ghaderi

Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University, Tabriz, I.R. IRAN

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