Facile Conversion of Epoxides to ۱,۲-Diacetates with NaOAc•۳H۲O/Ac۲O System

This study represents a highly efficient and regioselective ring-opening of epoxides with acetic anhydride in the presence of NaOAc·۳H۲O at solvent-free conditions. The ring-opening of different classes of epoxides were carried in oil bath (۷۰-۸۰ °C) to afford ۱,۲-diacetates in high to excellent yields

کلیدواژه ها:

Ac۲O ، ۱ ، ۲-Diacetates ، epoxides ، NaOAc•۳H۲O ، Ring-opening