Characterization of Sol-Gel Derived CuO@SiO۲ Nano Catalysts towards Gas Phase Reactions

One distinct concentration of copper ions was embedded into the silica matrix to xerogel form using copper source Cu(NO۳)۲∙۳H۲O. The xerogel samples were prepared with using hydrolysis and condensation reactions of TetraEthyl Ortho-Silicate (TEOS) by the sol-gel method. In this investigation, new molar ratio of H۲O/TEOS was determined to be ۱۱.۷. Also, the necessary amount of tri-hydrated copper nitrate was added to the solution in such a manner that the concentration of the copper oxide in final solution reach to ۱۰ wt. %. The prepared samples were characterized by Thermal Gravimetric Analysis (TGA), Transmission Electron Microscopy (TEM), surface area measurement (using BET method) and Thermal Program Reduction (TPR) methods. Finally, catalytic behavior of nano-composites was studied towards carbon monoxide (CO), nitrogen monoxide (NO) oxidation and di-nitrogen oxide (N۲O) decomposition reactions.The results were presented the systematic reactivity study of CO, NO oxidation and N۲O decomposition on dispersed copper oxide nano-catalysts over silica supports, in order to determine the ability of these materials to convert carbon monoxide, nitrogen monoxide and di-nitrogen oxide  to harmless species by different reaction paths at different temperatures.

کلیدواژه ها:

Copper oxide ، nano-catalyst ، Thermal treatment ، Gas phase