Wet Chemical Synthesis of Graphene Containing Co / Mn Co-doped NiONanocrystalline Materials: Efficient Electrode for Electrochemical Supercapacitors

Graphene containing Co and Mn co-doped NiOnanocrystallinematerials  (with composition graphene - Ni۰.۹۵Co۰.۰۲۵Mn۰.۰۲۵O۱-δ) were synthesized by chemical synthesis route and studied for potential application as electrode material for supercapacitors. The phase structure of the materials was characterized by XRD technique and the crystallographic parameters were found out and reported. FT-IR spectroscopy revealed the presence of M-O bond in the materials. The morphological phenomenon of the materials was studied by SEM and the particles were found to be spherical with an average grain size of ۱۴ – ۲۸ nm. EDAX analysis confirmed the presence of appropriate levels of elements in the samples. The in-depth morphological characteristics were also studied by HR-TEM (High-Resolution Tunneling Electron Microscopy). Cyclic Voltammetry (CV), charge-discharge, and electrochemical impedance measurements were carried out in an aqueous electrolyte (۶ mol/L KOH) to investigate the electrochemical performance of the graphene containing Co and Mn co-doped NiOnanocrystallinebased electrode materials and the material found to exhibit a specific capacitance of ۱۲۴۳ F/g at a current density of ۰.۵ A/g and hence these electrode materials can be used in electrochemical supercapacitors.

کلیدواژه ها:

Doped NiO with graphene ، Chemical Synthesis ، Electrode material ، Electrochemical supercapacitor applications