New Catalyst for Biodiesel Formation: Synthesis, Structural Elucidation and Quantum Chemical Calculations of New Ni(II) Complexes

سال انتشار: 1400
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 4

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شناسه ملی سند علمی:

JR_IJCCE-40-6_004

تاریخ نمایه سازی: 17 خرداد 1404

چکیده مقاله:

New Ni(II) complexes were synthesized from the coordination of the ligands derived from benzo[۱,۲-c]isoxazoles with Ni(II) cation.. The structure of the new complexes was characterized by elemental analyses, mass, and IR spectra. To gain a deeper insight into the geometry of Ni(II) complexes, a quantum chemical investigation was performed. The obtained results from experimental and theoretical arguments confirmed a square-planar geometry for Ni(II) complexes. These complexes were examined as homogeneous catalysts for the transesterification of corn oil with methanol. The structure of the obtained product was confirmed by ۱H NMR analysis. The catalytic results showed that the new Ni(II) complexes can be considered potential candidates for the development of a new catalytic system for biodiesel production.

نویسندگان

Shahin Sobhani

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN

Mehdi Pordel

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN

Safar Ali Beyramabadi

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRAN

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