V۲O۵-MoO۳ Catalysts Preparation and Performance Testing on the Oxidation of Benzene to Maleic Anhydride in a Fixed Bed Reactor

In this research, the selective oxidation of benzene to maleic anhydride (MAN) in a fixed-bed reactor was studied. The gas phase catalytic oxidation of benzene was carried outin a laboratory scale fixed bed reactor on the catalysts, which were prepared having two different compositions on silica gel. The effects of temperature, flow rates of benzene and air, and catalyst type on the reaction selectivity were investigated at normal atmospheric pressure. The experiments were performed at the temperature range of ۳۰۰°C to ۳۷۵ °C, the space-time (W/FB۰) range was from ۱*۱۰۶ to ۲.۵*۱۰۶ g.sec/mole, and the air/ benzene weight ratio changes were between ۱۶-۵۱. Experimental results show that the maximum conversion is obtained at ۳۷۵°C, at the space-time ۱.۳۳*۱۰۶ g.s/mol and at the benzene/air mol ratio ۴۱.۳۶ by using first catalyst. According to the experimental results, a difference between catalyst ۱ and ۲, it could not be seen. MAN conversion was observed for both catalysts and both catalysts are suitable for oxidation of benzene to MAN in a fixed bed reactor.

کلیدواژه ها:

Gas-phase oxidation ، Benzene ، maleic anhydride ، Fixed-bed reactor