Development of A Low-Cost Method for Determination of Sulfide Ions in Aluminate Solution of Bayer Process and Sulfide Removal Using Nitrate from It

Sulfide ions in the solution of the Bayer process can accelerate the corrosion of the equipment and increase the impurity of the final product. In the current investigation, sulfide ions concentration of the aluminate solution during the Bayer process was determined using an indirect and inexpensive method. The method did not require any advanced apparatus, which made it suitable for sulfide concentrations over the range of ۰.۰۰۱-۱ g/L. To investigate the source of sulfide ions in the aluminate solution, the chemical composition and crystalline structure of the bauxite used to produce alumina were characterized via XRF, XRD, and SEM analyses. The results demonstrated that the main source of sulfide ions was pyrite in bauxite. The advantages and disadvantages of sulfide removal method by nitrate from aluminate solution were investigated. Thermodynamically, the spontaneity of different half-reactions during the reduction of NO۳- and oxidation of S۲- was studied. Finally, a technique was proposed for the removal of sulfide ions in the aluminate solution by adding nitrate. Moreover, the effect of nitrate concentration on lowering of sulfide ions concentration was evaluated in practical conditions of the bauxite digestion during the Bayer process. The results demonstrated that in conditions of bauxite digestion (at ۲۷۰ °C, ۵۲ bar, and ۶۰ minutes) by adding ۲.۵ g/L nitrate ions, the majority of sulfide ions (more than ۹۶%) were eliminated and their undesirable effects were prevented.

کلیدواژه ها:

Determination ، Sulfide removal ، nitrate ، Aluminate ، Bayer process