A Sensitive Electrochemical Sensor Using a Dolomite-Graphite Composite for the Simultaneous Detection of Pb۲+ and Cd۲+

A sensitive electrochemical method for the detection of trace heavy metal ions such as lead Pb (II) and cadmium Cd (II) using a Carbon Graphite Electrode (CPE) chemically modified by a dolomite powder was applied. Firstly, local Moroccan dolomite was deeply characterized  in order to understand its chemical composition and morphological structure. The performance of this sensor is revealed by three electrochemical methods: Square Wave Voltammetry (SWV), Cyclic Voltammetry (CV), and Electrochemical Impedance Spectroscopy (EIS). The effect of preconcentration time, concentration effect, media pH, and interference ionic response to the electrochemical response of the working electrode were all investigated under various experimental settings. The SWV determination coefficient (R² (Pb (II)) = ۰.۸۳۸۵ and R² (Cd (II)) = ۰.۹۳۰۷) is lower than the cyclic voltammetry result (R² (Pb (II)) = ۰.۹۸۹ and R² (Cd (II)) = ۰.۹۷۷), showing the latter's superior predicting ability. Even in the presence of interfering ions, the suggested electrochemical sensor exhibits good repeatability and selectivity, with detection limits of ۰.۱۰۱۱۳ μM and ۰.۲۲۲۲۷ μM for Pb۲+ and Cd۲+, respectively. These values ​​obtained from the calibration curves of the substances studied reveal that the developed sensor showed excellent electroanalytical performances for the detection of heavy metal ions. According to Atomic Absorption Spectroscopy (AAS), the prepared electrode from CPE-dolomite showed a highly sensitive capacity toward cadmium detection with a content of ۱۷۸.۴۳ mM after mineralization of the electrode immersed in CdSO۴ solution. The same electrode was used to reduce the lead in which the resulting solution was analyzed involving a value of ۱۲۵.۲۳ mM.

کلیدواژه ها:

Electrochemical sensor ، Carbon graphite (CPE) ، Dolomite ، Lead (Pb) ، Cadmium (Cd)