Comparative Study of Carbon Dioxide and Methane Adsorption by Synthesized Fine Particles of SAPO-۳۴ Molecular Sieve

Fine particles Silicoaluminophosphate-۳۴ were synthesized by hydrothermal sol-gel method. The effect of crystallization time, as one of the important synthesis factors on particle size and crystallinity, kinetic and equilibrium adsorption, and selectivity of CO۲ / CH۴ has been studied in this work. The adsorption isotherms are obtained at moderate gauge pressures (۱۰۰-۳۰۰۰ kPa) and temperatures (۲۷۸, ۲۸۸ and ۲۹۸ K), and the equilibrium adsorption parameters as well as heat of adsorption are determined for the synthesized SAPO-۳۴. The observed adsorption selectivity of CO۲ to CH۴ was determined to be around eight for that sample with higher degree of crystallinity.The crystallinity, isotherm parameters, adsorption selectivity and heat of adsorption confirm that the synthesized fine particle of SAPO-۳۴ could be a good candidate for separation of CO۲ from CH۴.

کلیدواژه ها:

SAPO-۳۴ ، Adsorption ، Crystallization ، Carbon dioxide ، Methane ، Fine particles