Process Model Development and Optimal Kinetics for Fuel Desulfurization via a Novel Nano-Catalyst

سال انتشار: 1403
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 89

فایل این مقاله در 14 صفحه با فرمت PDF قابل دریافت می باشد

استخراج به نرم افزارهای پژوهشی:

لینک ثابت به این مقاله:

شناسه ملی سند علمی:

JR_IJCCE-43-11_004

تاریخ نمایه سازی: 16 خرداد 1404

چکیده مقاله:

The elimination of dibenzothiophenes (DBT) from kerosene via the catalytic oxidation desulfurization (ODS) process was studied using hydrogen peroxide as an oxidant and MnO۲/SnO۲ as a catalyst. The oxidation reaction was examined under various operating conditions, including reaction temperatures (۳۰−۷۵oC), batch time (۲۵-۱۰۰ min), and loading amounts of MnO۲ (۰, ۱, and ۵%). The catalysts were conducted in this work using the impregnation method to support MnO۲ nanoparticles on the surface of SnO۲. Mathematical modeling was established by gPROMS software to predict DBT concentration, and kinetic parameters and compare them with observed results. According to the results of this study, it was observed that the maximum DBT removal obtained was ۹۴% under the best operating conditions. The findings showed that the behavior of DBT removal was enhanced with rising temperature, batch time, and MnO۲ loading. The optimal process variables of ODS of DBT based on the maximum conversion of DBT were estimated by an optimization technique. Finally, it can be concluded that the synthesis of nano-catalysts improved the DBT removal and led to the production of ultra-deep desulfurization for eco-friendly kerosene fuel.

کلیدواژه ها:

نویسندگان

Awad E. Mohammed

AL-Hawija Technical College, Northern Technical University, Kirkuk, IRAQ

Jasim Humadi

Department of Petroleum and Gas Refining Engineering, College of Petroleum Processes Engineering, Tikrit University, Tikrit, IRAQ

Yousif S. Issa

Department of Petroleum and Gas Refining Engineering, College of Petroleum Processes Engineering, Tikrit University, Tikrit, IRAQ

Mustafa A. Ahmed

Ministry of Oil, Salahulden, IRAQ

Dhia Y. Aqar

Studies, Planning and Follow-up Directorate, Ministry of Oil, Baghdad, IRAQ

Ahmad A. Aabid

Petroleum Reservoir Engineering Department, College of Petroleum & Mining, Mosul University, Mosul, IRAQ

Mahmod A. Abdulqade

Oil Products Distribution Company (OPDC), Salahuldeen Branch, Tikrit, Ministry of Oil, IRAQ

Ghazwan S. Ahmed

Chemical Engineering Department, College of Engineering, Tikrit University, Tikrit, IRAQ

مراجع و منابع این مقاله:

لیست زیر مراجع و منابع استفاده شده در این مقاله را نمایش می دهد. این مراجع به صورت کاملا ماشینی و بر اساس هوش مصنوعی استخراج شده اند و لذا ممکن است دارای اشکالاتی باشند که به مرور زمان دقت استخراج این محتوا افزایش می یابد. مراجعی که مقالات مربوط به آنها در سیویلیکا نمایه شده و پیدا شده اند، به خود مقاله لینک شده اند :
  • Tripathi D., Singh R.K., Oxidative Desulfurization of Dibenzothiophene using Cobalt(II) ...
  • Bajraktari-Gashi Z., Ibrahimi I., Desulfurization in the Electro-Arc Furnace, Opportunity ...
  • Beshkoofeh S., Ghalami-Choobar B., Shahidian Z., Khosharay S., Preparation, Characterization, ...
  • Mohammed M.H., Gheni S.A., Hamad K.I., Mohammed H.M., Hmood Mahomood ...
  • Mohammed A.E., Gheni S.A., Mohammed W.T., Agricultural Waste-Based Microporous Catalysts ...
  • Sheibani S., Zare K., Mousavi Safavi S.M., Investigation of Oxidative ...
  • Liu J., Liu X., Yan R., Jia L., Cheng H., ...
  • Hensen E.J.M., Beer V.H.J., Van Veen J.A.R., Santen R.A., On ...
  • Hussain M., Song S.K., Ihm S.K., Synthesis of Hydrothermally Stable ...
  • Bose D., Design Parameters for a Hydro Desulfurization (HDS) unit ...
  • Veryasov G., Grilc M., Likozar B., Jesih A., Hydrodeoxygenation of ...
  • Grilc M., Likozar B., Levec J., Hydrodeoxygenation and Hydrocracking of ...
  • Akbari A., Fakhri H., Three Novel Sets of Cs۲H [PW۴Mo۸O۴۰] ...
  • Schmitz C., Datsevitch L., Jess A., Deep Desulfurization of Diesel ...
  • Jafar S.A., Nawaf A.T., Humadi J.I., Improving the Extraction of ...
  • Humadi J.I., Gheni S.A., Ahmed S.M.R., Abdullah G.H., Phan A.N., ...
  • Mei H., Mei B.W., Yen T.F., A New Method for ...
  • Attar A., Corcoran W.H., Desulfurization of Organic Sulfur Compounds by ...
  • Zannikos F., Lois E., Stournas S., Desulfurization of Petroleum Fractions ...
  • Otsuki S., Nonaka T., Takashima N., Oxidative Desulfurization of Light ...
  • Pant D., Joshi D., Upreti M.K., Kotnala R.K., Chemical and ...
  • Shiraishi Y., Tachibana K., Hirai T., Komasawa I., Desulfurization and ...
  • Dinamarca M.A., Ibacache-Quiroga C., Baeza P., Galvez S., Villarroel M., ...
  • Davoodi-Dehaghani F., Vosoughi M., Ziaee A.A., Biodesulfurization of Dibenzothiophene by ...
  • Bhasarkar J.B., Dikshit P.K., Moholkar V.S., Ultrasound Assisted Biodesulfurization of ...
  • Borzenkova N., Veselova I., Shekhovtsova T., Biochemical Methods of Crude ...
  • Dai Y., Qi Y., Zhao D., Zhang H., An Oxidative ...
  • Akbari A., Haji Andevary H., Catalytic Oxidative-Extractive Deep Desulfurization of ...
  • Figueras F., Influence of the Coordination on the Catalytic Properties ...
  • Mohammed H.R., "Functionalized Coated Activated Carbon for the Oxidative Desulfurization ...
  • Ghazwan S.A., Aysar T., Ban A., "Kinetics and Optimal Reaction ...
  • Humadi J.I., Aabid A.A., Mohammed A.E., Ahmed G.S., Abdulqader M.A., ...
  • Wadood T.M., Raghad F.K., Sheam B.A.A., Desulfurization of Diesel Fuel ...
  • Fathi M.I., Humadi J.I., Mahmood Q.A., Nawaf A.T., Ayoub R.S., ...
  • Ali N.M., Majeed E.M., Hassan Abdul Razzaq G., Humadi J.I., ...
  • Wadood T.M., Active Carbon from Date Stones for Phenol Oxidation ...
  • Abbas A.F., Ahmed M.J., Optimization of Activated Carbon Preparation from ...
  • Abbas A., Ahmed M., Mesoporous Activated Carbon from Datestones (Phoenix ...
  • Abdulmajeed Y.R., Al-Huda N., Mahmood J., Production of High Surface ...
  • Abdulqader M.A., Mohammed A.E., Saleh S.H., Al-Jubouri H.M.S., "Total Remediation ...
  • Mohammed A.E., Gheni S.A., Mohammed W.T., Abdulqader M.A., Converting Iraqi ...
  • Ren T.Z., Yuan Z.Y., Du G.H., Su B.L., Facile Preparation ...
  • Hassan S.M., Mannaa M.A., Ibrahim A.A., Nano-Sized Mesoporous Phosphated Tin ...
  • Manjunathan P., Marakatti V., Chandra S., Atul B., Shubhangi K., ...
  • Liao X., Wu D., Geng B., Lu S., Yao Y., ...
  • Zhou L., Du Y., Du X., Lei J., Enhancement of ...
  • Rasmuson A., Andersson B., Olsson L., Andersson R., Mathematical Modeling ...
  • Mohammed A.E., Jarullah A.T., Gheni S.A., Mujtaba I.M., Optimal Design ...
  • Mohammed A.E., Jarullah A.T., Gheni S.A., Mujtaba I.M., Significant Cost ...
  • Ahmed G., Humadi J., Aabid A., Mathematical Model, Simulation and ...
  • Humadi J.I., Issa Y.S., Aqar D.Y., Ahmed M.A., Ali Alak ...
  • Neumaier A., Mathematical Model Building, Springer, ۳۷–۴۳ (۲۰۰۴) ...
  • Näf U.G., Stochastic Simulation using gPROMS, Comput. Chem. Eng., ۱۸: ...
  • Humadi J.I., Nawaf A.T., Jarullah A.T., Ahmed M. A., Hameed ...
  • Humadi J.I., Shihab M.A., Ahmed G.S., Ahmed M. A., Abdullah ...
  • Saha B., Kumar S., Sengupta S., Green Synthesis of Nano ...
  • Humadi J.I., Khamees L.A., Saeed L.I., Improved Kerosene Quality with ...
  • Salman M.S., Jafar S.A., Abdullah G.H., Humadi J.I., Ahmed M.A., ...
  • Hamad K.I., Humadi J.I., Abdulkareem H.A., Al‐Salihi S., Farhan O.I., ...
  • Ahmed T.H., Hydrocarbon Phase Behavior, (۱۹۸۹) ...
  • Ramsay J.O., Principal Differential Analysis: Data Reduction by Differential Operators, ...
  • Adeyi A.A., Aberuagba F., Comparative Analysis of Adsorptive Desulphurization of ...
  • نمایش کامل مراجع