Synthesis of G-C۳N۴/Mxene Composite for Enhanced Photocatalytic Degradation of Eosin Y Dye in Aqueous Solutions Under Visible Light

سال انتشار: 1403
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 78

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شناسه ملی سند علمی:

JR_SUER-4-4_001

تاریخ نمایه سازی: 16 مهر 1403

چکیده مقاله:

In this study, MXene nanosheets were utilized as a co-catalyst to modify the graphitic carbon nitride photocatalyst and synthesize the g-C۳N۴/MXene composite. Eosin Y dye was employed as a model organic pollutant to evaluate the photocatalytic degradation performance. Eosin Y, an anionic dye, poses significant environmental and health risks due to its resistance to biodegradation, as well as its toxicity and carcinogenicity. To synthesize this composite, graphitic carbon nitride was initially produced using a simple thermal polymerization method. Subsequently, it was protonated and assembled with MXene nanosheets through a self-assembly process. The MXene nanosheets were synthesized using a Mild method. Characterization and confirmation of the successful synthesis of the g-C۳N۴/MXene composite were conducted through X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and energy-dispersive X-ray spectroscopy (EDS) analyses. The results of the Eosin Y degradation experiments indicated that the composite with a ۷% weight ratio of MXene nanosheets exhibited the highest photocatalytic performance among the various weight ratios tested. The incorporation of MXene nanosheets more than doubled the photocatalytic degradation efficiency of graphitic carbon nitride. The MCN۷ sample was able to remove ۹۸% of ۲۵ mg/L Eosin Y dye from an aqueous solution within ۱۲۰ minutes, using a photocatalyst dosage of ۰.۴ g/L. The findings of this study demonstrate that the integration of MXene nanosheets with graphitic carbon nitride significantly enhances the photocatalytic performance of graphitic carbon nitride in the degradation of organic pollutants.

نویسندگان

Mehran Bijari

Department of Environmental Technologies, Environmental Sciences Research Institute, Shahid Beheshti University, ۱۹۸۳۹۶۹۴۱۱, Tehran, Iran

Afsaneh Shahbazi

Department of Environmental Technologies, Environmental Sciences Research Institute, Shahid Beheshti University, ۱۹۸۳۹۶۹۴۱۱, Tehran, Iran

Vahid Vatanpour

Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University, ۱۵۷۱۹-۱۴۹۱۱ Tehran, Iran

Habibollah Younesi

Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University, ۴۶۴۱۴-۳۵۶, Noor, Iran

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