Synergistic Action of Hierarchical Porosity and Multifunctionality for Efficient Catalysis ofAsymmetric Reactions

Here, Q-HKUST-۱ possessing a Lewis acid site transformed into an excellent multifunctional chiral MOF(Q-HKUST-Cys), via post-synthetic modification by L-Cysteine. The Q-HKUST-Cys is an efficient catalyst forpromoting asymmetric ring-opening of epoxide, nitroaldol, and cycloaddition of CO۲ reactions under mildconditions.

کلیدواژه ها:

Defective-MOFs ، heterogeneous catalysis ، Pore functionalization.