Ast and Mild Asymmetric Catalysis utilizing Hierarchically Chiral Metal-OrganicFrameworks

A green method was applied for the synthesis of the first chiral Zr-fumarate framework, CMOF(ASP)through replacement of fumaric acid in MOF-۸۰۱ with L-aspartic acid. The results show that CMOF-۸۰۱(ASP) canreach maximum conversions and enantiomeric excess (ee%) in ring opening, nitroaldol, and solvent-freecycloaddition reactions at mildest conditions.

کلیدواژه ها:

Cluster-defect engineering ، Sustainable CO۲ utilization ، asymmetric catalysis