Synthesis of Efficient Porous Nanocomposite Based on Metal-Organic Framework UiO-۶۶-NH۲ On Metal-Organic Framework UiO-۶۶-(COOH)۲ Coated with ۵-Aminotetrazole/Pd-NPsfor Preparation of propargyl amines

This study aims to synthesize a highly efficient and reusable catalyst via a step-by-step post-synthesismodification of Metal Organic Frameworks (UiO-۶۶-NH۲)/ metal-organic framework UiO-۶۶-(COOH)۲ withnitrogen-rich organic ligand such as ۵-Aminotetrazole and hired as support for the preparation of (UiO-۶۶-NH۲)/UiO-۶۶-COOH @ ۵-aminotetrazole/Pd-NPs. This research is motivated to identify newly synthesized MOF-On-MOF nano-catalyst as an efficient MOF/MOF functionalized ۵-aminotetrazole via decoration of Palladium -nanoparticles. Moreover, the addition of N-rich organic ligands through post-synthesis modification alters thestructure of the final composite in favour of the progress of the A۳-coupling reaction.

کلیدواژه ها:

Metal Organic Framework ، ۵-Aminotetrazole ، Palladium Nanoparticles ، A۳-coupling