Bent Ladder-Like Heteropolynuclear Architectures through Cyanido Bridges and Pt(II)-Tl(I)Linkages: Exploration of Structural and Emission Properties in Solid State

The neutralized heteropolynuclear complexes, [{Pt(bzq)(C۶F۵)(CN)}Tl(THF)], ۱, with one-dimensionalheterometallic zigzag chain in crysal structure and [{Pt(dfppy)(C۶F۵)(CN)}Tl], ۲, with discrete closed hererooctametallicPt۴Tl۴ cluster with Pt(II)-Tl(I) bonds were synthesized. Both ۱ and ۲ exhibit a reversible mechanochromicand solvatochromic behavior with color/luminescence changes in solid state.

کلیدواژه ها:

Pt(II)-Tl(I) backbones ، photoluminescence ، heterometallic assemblies