Reusable and sustainable graphene oxide/metal–organic framework-۷۴/Fe۳O۴/polytyramine nanocomposite for simultaneous trace level quantification of five fluoroquinolones in egg samples by high performance liquid chromatography
سال انتشار: 1400
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 99
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شناسه ملی سند علمی:
JR_AMECJ-4-2_002
تاریخ نمایه سازی: 14 آذر 1402
چکیده مقاله:
A nanohybrid material termed graphene oxide/metal-organic
framework-۷۴/Fe۳O۴/polytyramine (GO/MOF-۷۴/Fe۳O۴/PTy) was
fabricated and applied in magnetic dispersive micro-solid phase
extraction (MD-μ-SPE) coupled with high performance liquid
chromatography (HPLC) for simultaneous determination of
fluoroquinolones compounds including, ofloxacin, ciprofloxacin,
lomefloxacin, enrofloxacin and sperfloxacin in egg samples. The
GO/MOF-۷۴/Fe۳O۴/PTy nanocomposite was fabricated through
an in situ synthesis of MOF-۷۴ in the presence of magnetic GO
and followed with an oxidative polymerization of tyramine using
horsedish peroxide (HRP) enzyme. The modifier agents improved
the merits of the nanoporous sorbent. Extraction protocols based
on GO/MOF nanocomposites have various benefit such as, the high
stability, the tunable porosity, the fast mast transfer and reasonable
enrichment factor. The fabricated material was characterized via
energy dispersive x-ray analysis (EDX), the scanning electron
microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR),
and the x-ray diffraction (XRD). The calibration curves revealed
linearity (۰.۹۹۹۲ ≤ r۲ ≤ ۰.۹۹۹۷) in the ranges of ۱.۰-۴۷۵.۰, ۰.۵-۳۵۰.۰,
۰.۵-۳۵۰.۰, ۰.۵-۳۷۵.۰ and ۱.۵-۳۰۰.۰ ng mL-۱ with limit of detections
(LODs, S/N=۳) of ۰.۳, ۰.۱, ۰.۲, ۰.۱ and ۰.۴ ng mL-۱ for ofloxacin,
ciprofloxacin, lomefloxacin, enrofloxacin and sperfloxacin,
respectively. The intra-assay (≤۷.۷%, n = ۹) and inter-assay (≤۷.۰%,
n = ۹) precisions along with accuracy less than ۹.۰% showed the
reliability of the method.
کلیدواژه ها:
Magnetic dispersive micro-solid phase extraction ، Metal–organic framework ، Graphene oxide ، Polytyramine ، Fluoroquinolones
نویسندگان
Fatemeh Pourbahman
Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
Mohsen Zeeb
Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
Amirhossein Monzavi
Department of Polymer and Textile Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
Zahra Khodadadi
Department of Applied Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran