Investigation of Acid Blue ۶۲ Dye Adsorption using SBA-۱۵/Polyaniline Mesoporous Nanocomposite: Kinetic and Thermodynamic Study

سال انتشار: 1396
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 165

فایل این مقاله در 18 صفحه با فرمت PDF قابل دریافت می باشد

استخراج به نرم افزارهای پژوهشی:

لینک ثابت به این مقاله:

شناسه ملی سند علمی:

JR_JHES-5-3_002

تاریخ نمایه سازی: 8 آذر 1402

چکیده مقاله:

Background and Purpose: This study aimed to investigate the adsorption of Acid Blue ۶۲ (AB۶۲) as an anionic dye from aqueous solution onto as SBA-۱۵/Polyaniline (SBA-۱۵/PAni) mesoporous nanocomposite a low-cost adsorbent and feasible. Materials and Methods: Fourier transform infra-red spectroscopy (FTIR), Filed Emission Scanning Electron Microscope (FESEM), Transmission Electron Microscope (TEM), X-ray Diffraction (XRD), and BET were used to examine the structural characteristics of obtained adsorbent. The effective parameters on batch adsorption process such as pH, dosage, and time were investigated and optimized. For determining the type of kinetic model, pseudo first order, pseudo second order, Elovich and intra-particle diffusion kinetic models were applied. Thermodynamic parameters such as changes in Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were calculated. Results: Maximum BET specific surface and pore volume on the adsorbent were ۲۲۴.۴ m۲ /g and ۰.۴۶ cm۳ /g, respectively. The obtained optimized condition was as follows: pH=۲, time=۶۰ min, temperature ۲۵° C, and adsorbent dose = ۰.۳ g/l. The adsorption kinetic data well-fitted by pseudo-second order kinetic equation. The negative values of ΔG° and ΔH° (- ۴.۰۱۲ KJ/mol) and the positive value of ΔS° (۰.۴۰۹ J/mol K) showed that the AB۶۲ adsorption process was spontaneous, physi-sorption, feasible and exothermic. Conclusion: SBA-۱۵/PAni can well be used as a low-cost surface adsorbent for removal of AB۶۲ from aqueous media.

کلیدواژه ها:

نویسندگان

Iman Akbartabar

Department of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran

Mohammad Esmail Yazdanshenas

۱. Department of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran

Habib-Allah Tayebi

۲. Department of Textile Engineering, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran

Navid Nasirizadeh

۱. Department of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran

مراجع و منابع این مقاله:

لیست زیر مراجع و منابع استفاده شده در این مقاله را نمایش می دهد. این مراجع به صورت کاملا ماشینی و بر اساس هوش مصنوعی استخراج شده اند و لذا ممکن است دارای اشکالاتی باشند که به مرور زمان دقت استخراج این محتوا افزایش می یابد. مراجعی که مقالات مربوط به آنها در سیویلیکا نمایه شده و پیدا شده اند، به خود مقاله لینک شده اند :
  • Zareyee D, Tayebi H, and Javadi SH. Preparation of polyaniline/activated ...
  • Gan Y, Tian Na, Tian X, Ma L, Wang W, ...
  • Anbia M, Salehi S. ۲۰۱۲; Removal of acid dyes from ...
  • Qin Q, Ma J, and Liu K. Adsorption of anionic ...
  • Muthukumar M, Sargunamani D, Selvakumar N, Rao JV. Optimisatio of ...
  • Shi B, Li G, Wang D, Feng C, Tang H. ...
  • Riera-Torres M, Gutiérrez-Bouzán C, Crespi M. Combination of coagulation– flocculation ...
  • Gupta VK, Jain R, Nayak A, Agarwal Sh, Shrivastava M. ...
  • Yang CH, Lee CC, Wen TC. Hypochlorite generation on Ru-Pt ...
  • https://doi.org/۱۰.۱۰۲۳/A:۱۰۰۴۰۳۱۸۰۴۳۱۳https://doi.org/۱۰.۱۰۲۳/A:۱۰۰۳۵۹۲۷۲۱۱۴۶Kornaros M, Lyberatos G. Biological treatment of wastewaters from a ...
  • Chu HC, Chen KM. Reuse of activated sludge biomass: I. ...
  • Zhu M, Lee L, Wang H, Wang Z. Removal of ...
  • Ai L, Zhou Y, Jiang J. Removal of methylene blue ...
  • Daneshvar N, Khataee AR, Rasoulifard MH, Pourhassan M. Biodegradation of ...
  • Sponza DT, Isik M. Decolorization and azo dye degradation by ...
  • Shu H, Huang C, and Chang M.Decolorization of mono-azo dyes ...
  • Vlyssides AG, Papaioannou D, Loizidoy M, Karlis PK, Zorpas AA. ...
  • Shukla P, Wang S, Sun H, Ang H, Tadé M. ...
  • Direct Blue ۷۱ Removal from Aqueous Solutions by Adsorption on Pistachio Hull Waste: Equilibrium, Kinetic and Thermodynamic Studies [مقاله ژورنالی]
  • Removal of Anionic Dyes (Direct Blue ۱۰۶ and Acid Green ۲۵) from Aqueous Solutions Using Oxidized Multi-Walled Carbon Nanotubes [مقاله ژورنالی]
  • Zazouli M A, Balarak D, Mahdavi Y, Ebrahimi M. Adsorption ...
  • Thu P, Dieu H, Phi H, Viet N, Kim S, ...
  • Kao H, Liao C, Palani A, Liao Y. One-pot synthesis ...
  • Anbia M, Hariri S. Removal of methylene blue from aqueous ...
  • Da'na E, Sayari A. Adsorption of heavy metals on amine-functionalized ...
  • Kleitz F, Czuryszkiewicz T, Solovyov L, and Lindén M. X-ray ...
  • Lee C, Liu S, Juang L, Wang C, Lin K, ...
  • De la Iglesia O, Pedernera M, Mallada R, Linc Z, ...
  • Punyapalakul P, Takizawa S. Selective adsorption of nonionic surfactant on ...
  • Zhao A, Samanta A, Sarkar P, and Gupta R. Carbon ...
  • Kamarudin KSN, Alias N. Adsorption performance of MCM-۴۱ impregnated with ...
  • Gil M, Tiscornia I, de la Iglesia O, Mallada R, ...
  • Sanz R, Calleja G, Arencibia A, Sanz- Pe´rez ES. CO۲ ...
  • Bhagiyalakshmi M, Yun L, Anuradha R,Jang H. Utilization of rice ...
  • Ballav N, Maity A, Mishra SB. High efficient removal of ...
  • Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi M, ...
  • Ansari R, and Mosayebzadeh Z. Removal of Basic Dye Methylene ...
  • Bhaumik M, Maity A, Srinivasu VV, Onyango MS. Removal of ...
  • Mansour MS, Ossman ME, Farag HA. Removal of Cd (II) ...
  • Krishnani KK, Srinives S, Mohapatra BC, Bodd, VM, Hao J, ...
  • Shafiabadi M, Dashti A, Tayebi H. Removal of Hg (II) ...
  • Tayebi H, Yazdanshenas M E, Rashidi A, Khajavi R, Montazer ...
  • Tayebi H, Dalirandeh Z, Shokuhirad A, Mirabi A, Binaeian E. ...
  • Bakala P, Briot E, Salles L, Bre´geault J. Comparison of ...
  • Li Q, Yu H, Song J, Pan X, Liu J, ...
  • Katiyar A, Ji L, Smirniotis P, Pinto NG.Protein adsorption on ...
  • Ullah R, Atilhan M, Aparicio S, Canlier A, Yavuz CT. ...
  • Bui T, Choi H. Adsorptive removal of selected pharmaceuticals by ...
  • Yiu HHP, Wright PA, Botting NP. Enzyme immobilisation using SBA-۱۵ ...
  • Mureseanu M, Reiss A, Stefanescu I, David E, Parvulescu V, ...
  • Wu C. Adsorption of reactive dye onto carbon nanotubes: Equilibrium, ...
  • Kumar PS, Ramalingam S, Senthamarai C, Niranjanaa M, Vijayalakshmi P, ...
  • Indra DM, Vimal CS, Nitin KA. Removal of Orange-G and ...
  • Peng X, Huang D, Odoom-Wubah T, Fu D, Huang J, ...
  • نمایش کامل مراجع