Synthesis, characterization, and catalytic performance of Pd/CNT-MOFnanocatalysts in C-C bond formation reactions

Nanocomposites generally have wide applications in various fields, including drug deliveryand catalytic activity for organic synthesis. In this project, an attempt has been made to synthesizea heterogeneous catalyst based on metal-organic frameworks and magnetic carbon nanotubes. Aporous multifunctional palladium-based metal-organic framework (MOF) was developed throughcombined covalent and dative by multi-wall carbon nanotube (MWCNT)[۱]–[۳]. A novelmagnetic metal-organic framework (MMOF) consisting of supported Pd/CNT has been fabricatedin this regard. As a result, the fabricated magnetic porous catalyst exhibited catalytic activity inSuzuki-Miyaura cross-coupling reactions. Some of the essential advantages of the synthesizedcatalyst are; high catalytic activity, short reaction times, mild conditions, high thermal stability,and reusability. Moreover, his porous magnetic nanomaterial can be used as a new support toimmobilize other metals in different catalytic reactions

کلیدواژه ها:

MWCNT ، Palladium chloride ، Suzuki Reaction ، and nanocatalyst