[Cu(lys bipy)]Cl/GO Synthesis, Identification and Application inOxidation of Olefine

In this research, [Cu(lysbipy)] Cl complex[۱] was prepared. Graphene oxide was synthesizedby the modified Hummers method [۲] and functionalized with ۳-chloropropyltrimethoxysilaneand the complex is deposited on functionalized graphene oxide )[Cu(lysbipy)]Cl/GO( [۳].[Cu(lysbipy]Cl and [Cu(lysbipy)]Cl/GO used as a catalyst in the oxidation of olefins. Thesynthesized complexes was identified by EDX, ICP, SEM, FTIR and XRD[۴] processes. Thecatalytic results of the prepared complex analyzed by GC and GC–MS instruments and showedthat the catalytic activity of [Cu(lysbipy)]Cl/GO in oxidation reaction in of α-methylstyreneoptimal conditions ۴ hours, Acetonitrile solvent, ۰.۰۲۵ g of catalysts and using tert-butylhydroperoxide as an oxidant ۹۷% conversion with selectivity of ۸۴% of acetophenone .

کلیدواژه ها:

Graphen oxide ، Oxidation ، Bipyridine ، Lysine