Application of Chlorophyll Extracted from Spinach as a Green and affordable Catalyst for the Synthesis of Tetrahydrobenzo[b]pyran and Pyrano[c]chromene
محل انتشار: دوفصلنامه تحقیقات شیمی آلی، دوره: 6، شماره: 2
سال انتشار: 1399
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 291
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شناسه ملی سند علمی:
JR_ORGC-6-2_004
تاریخ نمایه سازی: 3 مهر 1402
چکیده مقاله:
Chlorophyll is a natural pigment used for the synthesis of organic substances for instance sugars. At mild conditions, chlorophyll was employed as a green catalyst for the synthesis of tetrahydrobenzo[b]pyran and ۳,۴-dihydropyrano[c]chromene from the condensation between aromatic aldehydes, malononitrile, and ۴-hydroxy-۲H-chromen-۲-one is an active enolic compound. This methodology has a considerable number of advantages such as mild conditions, natural, affordable catalyst, excellent yields, eco-friendly and, short reaction time. Another point worth mentioning is that purification of the products does not require sophisticated methods like column chromatography.
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نویسندگان
Moheb Shirzaei
Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P. O. Box۹۸۱۳۵-۶۷۴, Zahedan, Iran
Ebrahim Mollashahi
Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P. O. Box ۹۸۱۳۵-۶۷۴ Zahedan, Iran
Malek Taher Maghsoodlou
Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P. O. Box۹۸۱۳۵-۶۷۴, Zahedan, Iran
Mojtaba Lashkari
Faculty of Sciences, Velayat University, Iranshahr, Iran