Preparation of MgCl۲-Supported Ziegler-Natta Catalyst for Ethylene Polymerization
سال انتشار: 1401
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 138
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شناسه ملی سند علمی:
OGPC04_131
تاریخ نمایه سازی: 25 اردیبهشت 1402
چکیده مقاله:
This article describes a highly properties of MgCl۲-supported Ziegler-Natta catalyst using in ethylene polymerization. Catalyst immobilization was performed on anhydrous MgCl۲.The effect of initial preparation on final product was investigated. Scanning electron micrpscopy showed that the catalyst particles exhibit an amorphous shape. In addition, polymerization of ethylene was carried out using the supported catalyst, triethylaluminium as a cocatalyst in slurry phase. According to the obtained results, it was found the heterogeneous catalyst displayed high activity, high bulk density and excellent hydrogen sensitivity. The polyethylene produced by the catalyst has a narrow particle size distribution with a low fine powder content which competitive with traditional grades.
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نویسندگان
Seyed Mehdi Ghafelebashi
National Petrochemical Company, Petrochemical Research and Technology Company, Tehran, Iran
Fatemeh Shahsavari
National Petrochemical Company, Petrochemical Research and Technology Company, Tehran, Iran
Mahmoud Daneshgar
National Petrochemical Company, Petrochemical Research and Technology Company, Arak, Iran
Farideh Azimfar
National Petrochemical Company, Petrochemical Research and Technology Company, Tehran, Iran