Comparing Anomeric Effects of halo[۱,۴]dioxane and halo[۱,۴]dithian in Solvent and Gas Phases

The replacement of carbon by other elements p roduces ch anges in several structural parameters such as stereo-c hemical features and consequently affects the conformational charac teristics of the molecule. The ano meric effect plays an im portant principal role in the stereo-chemical outcome by guiding the relevant electronegati ve substituents into an axial positi on [۱-۳]. H ence perception of the general rul es that are controller of stereo-chemical effect s, have great help in interpreting the properties o f molecules and their reactivity

کلیدواژه ها:

Anom eric effect ، Computation ، Halo[۱ ، ۴]dioxane ، Halo[۱ ، ۴]dithi ane.