Theoretical in vestigatio n of the i nteraction s between Li atom and eleme nts from first to fourth rows of periodi c table

The organolithium compounds with their special bon d properties have critical role in organic synthe sis [۱]. Also there has been a gre at deal of in terest in st udy of lithiu m bond [۹ ۰-۹۳]. However, according to our knowledge, there is rare information about the nature of lithium bond. In this paper, the bond nature of dimmer com plexes containing lithium and ele ments from first to fourth rows of p eriodic table are studied using the a b initio and atom in mol ecule (AIM ) methods.

کلیدواژه ها:

Lithiu m bond ، AIM analysis ، B۳LYP calc ulation ، organolithium compounds